Adhesion layer for Pt on SiO2

ABSTRACT

Si, Al, Al plus TiN, and Ir02 are used as adhesion layers to prevent peeling of noble metal electrodes, such as Pt, from a silicon dioxide (5i0 2 ) substrate in capacitor structures of memory devices.

CROSS-REFERENCE TO RELATED APPLICATIONS

[0001] This application is a divisional of U.S. application Ser. No. 10/408,339, filed Apr. 7, 2003, the disclosure of which is incorporated herein.

BACKGROUND OF THE INVENTION

[0002] The present invention relates to integrated circuit (IC) memory devices and, more particularly, to the inclusion of one or more thin layers, such as Si, Al, Ir0₂, or Al plus TiN, as an adhesion layer between a noble metal layer, such as Pt, and a silicon dioxide (Si0₂)layer to form the electrode for high-k dielectric Dynamic Random Access Memory (DRAM) and Ferroelectric Random Access Memory (FRAM) applications.

[0003] Capacitors with high dielectric constant (high-k) materials as the dielectric are increasingly used in high density devices. The high-k dielectrics used in DRAM devices are generally formed at a high temperature oxidation ambient, as are ferroelectric materials used in FRAM devices. To avoid oxidation of the electrodes at these high temperatures, noble metal electrodes are used with the dielectric. Platinum (Pt) electrodes are typically used for the high-k dielectric capacitors in DRAM devices and for FRAM devices because of its excellent oxidation resistance and high work function. However, Pt poorly adheres to silicon dioxide and results in peeling of the Pt at various process steps, such as during the formation of the capacitor and during the following Back End of Line (BEOL) processes. To prevent peeling, an intermediate adhesion layer may be added between the Pt and SiO₂ layers. Currently, the adhesion layers used include Ti, TaSiN or TiN.

[0004] Though these materials can improve the adhesion between the Pt and SiO₂ layers in the “as-deposited” state, roughening of the Pt surface or a local peeling has been observed after the subsequent annealing step which is typically at a temperature of 500 to 580° C. in an oxygen ambient. Further, when high-k dielectric and ferroelectric layers are deposited at temperatures below 500° C., the layers have degraded film quality with decreased capacitance, which degrades the performance of the device.

[0005] It is therefore desirable to provide an improved adhesion layer between the noble metal electrodes and the SiO₂ layers. It is also desirable to provide an adhesion layer that prevents the peeling of the noble metal electrodes of the capacitor structures.

SUMMARY OF THE INVENTION

[0006] The present invention provides one or more adhesion layers which prevent the Pt electrode from peeling from the SiO₂. Such layers include IrO₂, Si, Al, or Al plus TiN as the adhesion layer.

[0007] According to an aspect of the invention, in a semiconductor capacitor structure formed on a silicon dioxide (SiO₂) substrate and having a noble metal electrode, an adhesion layer is disposed between the electrode and the SiO₂ substrate. The adhesion layer is selected from a group consisting of silicon (Si), aluminum (Al), aluminum (Al) plus titanium nitride (TiN) and iridium oxide (IrO₂).

[0008] According to a further aspect of the invention, an adhesion layer is selected from a group consisting of Si, Al, Al plus TiN, and IrO₂ and is disposed between a noble metal layer and a silicon dioxide layer.

[0009] According to another aspect of the invention, a high dielectric constant (high-k) capacitor structure is fabricated. An adhesion layer is deposited on a SiO₂ substrate. The adhesion layer is selected from a group consisting of Si, Al, Al plus TiN, and IrO₂. A noble metal bottom electrode is deposited on the adhesion layer.

[0010] In accordance with this aspect of the invention, a high-k dielectric material is deposited on the bottom electrode. A top electrode is deposited on the high-k dielectric layer, and the top electrode and the high-k dielectric are patterned. An insulation layer is deposited thereon, and vias are opened in the insulation layer. A metal pad layer is deposited in the vias and atop the insulation layer, and the metal pad layer is patterned.

[0011] According to a still further aspect of the invention, a 3-dimensional capacitor structure is fabricated. A silicon dioxide layer is deposited on a substrate, and vias are opened in the silicon dioxide layer. Polycrystalline silicon is deposited into the vias, and the polycrystalline silicon is planarized and recessed back to form poly plugs in the vias. A barrier layer is deposited in the vias, and the barrier layer is planarized. An adhesion layer is deposited atop the barrier layer and the SiO₂ layer. The adhesion layer is selected from a group consisting of Si, Al, Al plus TiN, and IrO₂. A noble metal bottom electrode is deposited on the adhesion layer.

BRIEF DESCRIPTION OF THE DRAWINGS

[0012] The foregoing and other objects, aspects and advantages will be better understood from the following detailed description of the invention with reference to the drawings in which:

[0013]FIG. 1 is a graph illustrating x-ray diffraction analysis data and showing the stability of IrO₂ at temperatures of up to 750° C.

[0014]FIG. 2 is a cross-sectional view showing a planar capacitor structure of a device according to an embodiment of the invention.

[0015]FIG. 3 is a cross-sectional view showing a first three-dimensional capacitor structure of a device according to another embodiment of the invention.

[0016]FIG. 4 is a cross-sectional view showing a second three-dimensional capacitor structure of a device according to a further embodiment of the invention.

DETAILED DESCRIPTION OF THE INVENTION

[0017] The invention is directed to the use of one or more layers, such as IrO₂, Si and Al plus TiN, that improve adhesion between an electrode layer and a SiO₂ layer.

[0018] IrO₂, as an example, has a good adhesion to silicon oxide as can be predicted by its oxygen bonding nature. IrO₂ remains stable up to 750° C. when exposed to an oxygen ambient, as shown in FIG. 1. Further, polycrystalline IrO₂ is conductive and can serve as a part of the electrode.

[0019] Alternatively, thin Si or Al layers can form a uniform thin silicon oxide or aluminum oxide layer underneath a Pt electrode to improve the adhesion of Pt on SiO₂ layer without decreasing dielectric film quality on the Pt. TABLE 1 Adhesion Test Results Adhesion Layer and Thickness Pt Thickness Adhesion (Mpam1/2) None 1000 Å Failed TiN, CVD, 50 Å 1000 Å <0.16  TaSiN, 250 Å 2500 Å 0.24 Ti, PVD, 50 Å 1000 Å 0.26 Al, 100 Å 1000 Å 0.23 Al, 100 Å, +Ti, 200 Å 1000 Å 0.32 Poly Si, 50 Å 1000 Å 0.30

[0020] Table 1 shows the adhesion properties of various materials after exposure in an oxygen ambient at 640° C. for five minutes. Samples with a known chemical vapor deposited (CVD) TiN adhesion layer could not be tested since its adhesion was less than 0.16. Samples with known Ti or TaSiN adhesion layers had improved adhesion over the CVD physical vapor deposition (PVD) but were not suitable because of dielectric layer degradation on a Pt/Ti or TaSiN/SiO₂ structure. Better or at least comparable adhesion was obtained for samples with a polycrystalline Si, Al, or Al plus Ti adhesion layers of the invention.

[0021] To test the adhesion, a planar capacitor structure, such as is shown in FIG. 2, was prepared by first depositing an adhesion layer 21 on a SiO₂ layer atop a substrate (not shown). The adhesion layer is preferably Si, Al, Al plus Ti or IrO₂. A Pt bottom electrode 23 is then deposited atop the adhesion layer 21. A high-k dielectric 24 is then deposited atop the adhesion layer, and a top electrode 25 (Pt) is deposited thereon. The high-k dielectric may be a (Ba,Sr)TiO₃ (BST) material. The top electrode 25 and the high-k dielectric 24 are then patterned and an insulation (SiO₂) layer 26 is thereafter deposited atop this structure. Vias are then opened in the SiO₂, and a Al or W a metal pad layer 27 is deposited in and on top of the vias and is then patterned.

[0022] Electrical testing results using the planar capacitor structure shown in FIG. 2 show essentially no change in the capacitance of the dielectric layer when using a poly Si adhesion layer, as Table 2 shows. TABLE 2 Electrical Test Results Adhesion Layer Capacitance (pF) None 350-400 Poly Si, 50 Å 350-400

[0023] The adhesion layers of the invention may be used in any integration scheme where adhesion of the electrode to the SiO₂ layer is of importance. Without limiting the scope of the invention, two examples using three-dimensional capacitor structures on devices for a DRAM application are now described.

[0024] Referring to FIG. 3, a SiO₂ layer 31 is formed on a device substrate (not shown). Vias are opened in the SiO₂ layer 31, and a polycrystalline Si layer 32 is deposited on top of the SiO₂ and into the vias. The polycrystalline Si is planarized to remove any material atop the SiO₂ layer, using a chemical mechanical polish (CMP) process, and the polysilicon is then recessed back, leaving poly plugs in the vias between the surface of the SiO₂ layer. Next, a barrier layer 33 is deposited atop the SiO₂ layer and the poly plugs, and the barrier layer is likewise subjected to a CMP process. An adhesion layer 34 is then deposited, and a Pt bottom electrode 35 is deposited atop the adhesion layer. If a conductive adhesion layer is used, such as IrO₂ the bottom electrode is deposited directly onto the adhesion layer. Alternatively, if a non-conductive adhesion layer is used, the part of the adhesion layer that is over the barrier layer is removed, and then the bottom electrode 35 is then deposited. Thereafter, the bottom electrode layer is patterned to form a three-dimensional structure (not shown). A high-k dielectric, such as BST, is then deposited and is covered with Pt top electrode layer to form the capacitor structure.

[0025] An alternative three-dimensional structure is shown in FIG. 4. First, a SiO₂ layer 41 is deposited on a device substrate (not shown). Vias are then opened in the SiO₂ layer, and a polycrystalline Si layer 42 is formed in the vias and atop the SiO₂. The polycrystalline Si is then planarized using a CMP process and recessed back, thereby leaving poly plugs in the vias. Next, a barrier layer 43 is deposited and subjected to a CMP process. A SiO₂ layer 44 is deposited and then patterned to form a three-dimensional structure, and an adhesion layer 45 is deposited thereon. A bottom (Pt) electrode 46 is deposited directly on the adhesion layer when the adhesion layer is conductive, such as when IrO₂ is used. Alternatively, the adhesion layer is removed in the regions above the barrier layer 43 and the bottom electrode is thereafter deposited. The top planar part of the bottom electrode 46 is then removed (not shown), and a high-k dielectric, such as BST, is deposited and covered with a Pt layer to form capacitors.

[0026] While the invention has been described in terms of preferred embodiments, those skilled in the art will recognize that the invention can be practiced with modification within the spirit and scope of the appended claims. 

1. A method of fabricating a high dielectric constant (high-k) capacitor structure, said method comprising: depositing an adhesion layer on a SiO₂ substrate, said adhesion layer being selected from the group consisting of Si, Al, Al plus TiN, and SiO₂; and depositing a noble metal bottom electrode on said adhesion layer.
 2. The method of claim 1 further comprising: depositing a high-k dielectric material on said bottom electrode; depositing a top electrode on said high-k dielectric layer; patterning said top electrode and said high-k dielectric layer; depositing an insulation layer thereon; opening vias to said top electrode in the insulation layer; depositing a metal pad layer in said vias and atop said insulation layer; and patterning the metal pad layer.
 3. The method recited in claim 1 wherein said bottom electrode is Pt
 4. The method recited in claim 2 wherein said top electrode is Pt.
 5. The method recited in claim 2 wherein said insulation layer is SiO₂.
 6. The method recited in claim 2 wherein said metal pad layer is Al or W.
 7. A method of fabricating a three-dimensional capacitor structure, comprising the steps of: depositing a Si0₂ layer on a substrate; opening vias in said SiO₂ layer; depositing polycrystalline Si into said vias; planarizing and recessing back said polycrystalline Si to form poly plugs in said vias; depositing a barrier layer in said vias atop said poly plugs; planarizing said barrier layer; depositing an adhesion layer atop said barrier layer and said SiO₂ layers, said adhesive layer being selected from the group consisting of Si, Al, Al plus TiN, and IrO₂; and depositing a noble metal bottom electrode on said adhesive layer.
 8. The method recited in claim 7 wherein said adhesion layer is conductive.
 9. The method recited in claim 8 wherein said adhesion layer is Ir0₂.
 10. The method recited in claim 7 wherein said adhesion layer is a non-conductive layer, and said method further comprises: removing a portion of said adhesion layer that is above said barrier layer before depositing said bottom electrode.
 11. The method recited in claim 7 wherein said bottom electrode is Pt.
 12. The method recited in claim 7 further comprising: patterning said bottom electrode to form a three-dimensional structure; depositing a high-k dielectric layer thereon; and depositing a top electrode on said high-k dielectric layer.
 13. The method recited in claim 12 further comprising: depositing and patterning a Si0₂ layer to form a three-dimensional structure prior to depositing said adhesion layer.
 14. The method recited in claim 13 further comprising: removing a top planar part of said bottom electrode; depositing a high-k dielectric layer; and depositing a top electrode
 15. The method recited in claim 14 wherein said bottom and top electrodes are Pt. 